Class information for:
Level 1: GRUNWALD WINSTEIN EQUATION//SOLVOLYSIS//EXTENDED GRUNWALD WINSTEIN EQUATION

Basic class information
Class id #P Avg. number of
references		 Database coverage
of references
7873 1318 36.7 40%


Bar chart of Publication_year

Last years might be incomplete

Hierarchy of classes
The table includes all classes above and classes immediately below the current class.


Cluster id Level Cluster label #P
5 4 CHEMISTRY, ORGANIC//CHEMISTRY, INORGANIC & NUCLEAR//CHEMISTRY, MULTIDISCIPLINARY 1745167
654 3       POLYOXYMETHYLENE DIMETHYL ETHERS//CROSS INTERACTION CONSTANT//PSEUDOACID 11347
1417 2             CROSS INTERACTION CONSTANT//GRUNWALD WINSTEIN EQUATION//PYRIDINOLYSIS 7994
7873 1                   GRUNWALD WINSTEIN EQUATION//SOLVOLYSIS//EXTENDED GRUNWALD WINSTEIN EQUATION 1318

Terms with highest relevance score


rank Term termType Chi square Shr. of publ. in
class containing
term		 Class's shr. of
term's tot. occurrences		 #P with
term in
class
1 GRUNWALD WINSTEIN EQUATION authKW 1343646 4% 100% 58
2 SOLVOLYSIS authKW 715057 8% 30% 102
3 EXTENDED GRUNWALD WINSTEIN EQUATION authKW 648657 2% 100% 28
4 SOLVENT NUCLEOPHILICITY authKW 231663 1% 100% 10
5 KINETIC SOLVENT ISOTOPE EFFECT authKW 154435 1% 67% 10
6 SOLVENT KINETIC ISOTOPE EFFECT authKW 134781 1% 73% 8
7 IONIZING POWER authKW 115832 0% 100% 5
8 SN2 MECHANISM authKW 111844 1% 37% 13
9 YUKAWA TSUNO EQUATION authKW 93814 1% 45% 9
10 SOLVOLYSES authKW 82734 0% 71% 5

Web of Science journal categories


Rank Term Chi square Shr. of publ. in
class containing
term		 Class's shr. of
term's tot. occurrences		 #P with
term in
class
1 Chemistry, Organic 12697 44% 0% 584
2 Chemistry, Multidisciplinary 8686 52% 0% 686
3 Chemistry, Physical 810 19% 0% 250
4 Geology 12 1% 0% 8
5 Education, Scientific Disciplines -0 0% 0% 2
6 Social Sciences, Interdisciplinary -1 0% 0% 2
7 Chemistry, Inorganic & Nuclear -1 1% 0% 11
8 Materials Science, Biomaterials -2 0% 0% 1
9 Spectroscopy -2 0% 0% 5
10 Physics, Atomic, Molecular & Chemical -3 1% 0% 12

Address terms


Rank Term Chi square Shr. of publ. in
class containing
term		 Class's shr. of
term's tot. occurrences		 #P with
term in
class
1 KIEVSKII POLITEKHNICHESKII 41180 0% 44% 4
2 BIOCHEM PL CHEM 39226 1% 14% 12
3 SCI CHEM HIGASHI KU 24755 1% 8% 13
4 KIEV POLYTECH 24634 1% 6% 19
5 CHEM I19 23166 0% 100% 1
6 CHIM BIOORGAN ORGAN PHYS CNRS ERA 685 23166 0% 100% 1
7 ELE OQUIM CINETICA 23166 0% 100% 1
8 FOSSIL FUELS GEOL GEOCHEM 23166 0% 100% 1
9 KIEVSKII POLITEKHN 23166 0% 100% 1
10 KIEVSKII POLITEKHN SKII 23166 0% 100% 1

Journals


Rank Term Chi square Shr. of publ. in
class containing
term		 Class's shr. of
term's tot. occurrences		 #P with
term in
class
1 JOURNAL OF PHYSICAL ORGANIC CHEMISTRY 58854 7% 3% 93
2 JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 33619 8% 1% 109
3 JOURNAL OF ORGANIC CHEMISTRY 13489 13% 0% 173
4 BULLETIN OF THE KOREAN CHEMICAL SOCIETY 12380 6% 1% 83
5 JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 8290 14% 0% 183
6 ORGANIC REACTIVITY 5665 1% 3% 8
7 ADVANCES IN PHYSICAL ORGANIC CHEMISTRY 4899 0% 4% 5
8 ZHURNAL OBSHCHEI KHIMII 3884 3% 0% 37
9 JOURNAL OF CHEMICAL RESEARCH-S 3645 2% 1% 22
10 RUSSIAN JOURNAL OF GENERAL CHEMISTRY 2926 2% 0% 29

Author Key Words


Rank Term Chi square Shr. of publ. in
class containing
term		 Class's shr. of
term's tot. occurrences		 #P with
term in
class		 LCSH search Wikipedia search
1 GRUNWALD WINSTEIN EQUATION 1343646 4% 100% 58 Search GRUNWALD+WINSTEIN+EQUATION Search GRUNWALD+WINSTEIN+EQUATION
2 SOLVOLYSIS 715057 8% 30% 102 Search SOLVOLYSIS Search SOLVOLYSIS
3 EXTENDED GRUNWALD WINSTEIN EQUATION 648657 2% 100% 28 Search EXTENDED+GRUNWALD+WINSTEIN+EQUATION Search EXTENDED+GRUNWALD+WINSTEIN+EQUATION
4 SOLVENT NUCLEOPHILICITY 231663 1% 100% 10 Search SOLVENT+NUCLEOPHILICITY Search SOLVENT+NUCLEOPHILICITY
5 KINETIC SOLVENT ISOTOPE EFFECT 154435 1% 67% 10 Search KINETIC+SOLVENT+ISOTOPE+EFFECT Search KINETIC+SOLVENT+ISOTOPE+EFFECT
6 SOLVENT KINETIC ISOTOPE EFFECT 134781 1% 73% 8 Search SOLVENT+KINETIC+ISOTOPE+EFFECT Search SOLVENT+KINETIC+ISOTOPE+EFFECT
7 IONIZING POWER 115832 0% 100% 5 Search IONIZING+POWER Search IONIZING+POWER
8 SN2 MECHANISM 111844 1% 37% 13 Search SN2+MECHANISM Search SN2+MECHANISM
9 YUKAWA TSUNO EQUATION 93814 1% 45% 9 Search YUKAWA+TSUNO+EQUATION Search YUKAWA+TSUNO+EQUATION
10 SOLVOLYSES 82734 0% 71% 5 Search SOLVOLYSES Search SOLVOLYSES

Core articles
The table includes core articles in the class. The following variables is taken into account for the relevance score of an article in a cluster c:
(1) Number of references referring to publications in the class.
(2) Share of total number of active references referring to publications in the class.
(3) Age of the article. New articles get higher score than old articles.
(4) Citation rate, normalized to year.


Rank Reference # ref.
in cl.		 Shr. of ref. in
cl.		 Citations
1 BENTLEY, TW , CHOI, H , KOO, IS , KEVILL, DN , (2017) POSITIONING SOLVOLYSES WITHIN THE S(N)2-S(N)1 AND S(N)3-S(N)2 SPECTRUM OF REACTION MECHANISMS.JOURNAL OF PHYSICAL ORGANIC CHEMISTRY. VOL. 30. ISSUE 1. P. - 48 91% 1
2 KEVILL, DN , D'SOUZA, MJ , (2008) SIXTY YEARS OF THE GRUNWALD-WINSTEIN EQUATION: DEVELOPMENT AND RECENT APPLICATIONS.JOURNAL OF CHEMICAL RESEARCH. VOL. . ISSUE 2. P. 61-66 83 94% 22
3 BENTLEY, TW , (2015) CALCULATED THIRD ORDER RATE CONSTANTS FOR INTERPRETING THE MECHANISMS OF HYDROLYSES OF CHLOROFORMATES, CARBOXYLIC ACID HALIDES, SULFONYL CHLORIDES AND PHOSPHOROCHLORIDATES.INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES. VOL. 16. ISSUE 5. P. 10601 -10623 64 91% 3
4 DVORKO, GF , PONOMAREVA, EA , PONOMAREV, NE , ZALIZNYI, VV , KOSHCHII, IV , (2007) NATURE OF SOLVATION EFFECTS AND MECHANISM OF HETEROLYSIS OF TERT-ALKYL HALIDES.RUSSIAN JOURNAL OF GENERAL CHEMISTRY. VOL. 77. ISSUE 9. P. 1535-1558 68 81% 2
5 CHOI, H , KOO, IS , (2012) CORRELATION OF THE RATES OF SOLVOLYSES OF 4-METHYLTHIOPHENE-2-CARBONYL CHLORIDE USING THE EXTENDED GRUNWALD-WINSTEIN EQUATION.BULLETIN OF THE KOREAN CHEMICAL SOCIETY. VOL. 33. ISSUE 2. P. 499-504 50 94% 1
6 DVORKO, GF , PONOMAREVA, EA , (2010) EFFECT OF NUCLEOPHILIC SOLVENT ON THE KINETIC PARAMETERS OF THE REACTIONS OF UNIMOLECULAR HETEROLYSIS. MECHANISM OF THE COVALENT BOND HETEROLYSIS.RUSSIAN JOURNAL OF GENERAL CHEMISTRY. VOL. 80. ISSUE 8. P. 1615-1625 56 86% 3
7 DVORKO, GF , PONORNAREVA, EA , PONOMAREV, ME , STAMBIRSKY, MV , (2007) NATURE OF SALT EFFECTS AND MECHANISM OF COVALENT BOND HETEROLYSIS.PROGRESS IN REACTION KINETICS AND MECHANISM. VOL. 32. ISSUE 2. P. 73-118 58 89% 5
8 DVORKO, GF , PONOMAREVA, EA , PONOMAREV, NE , (2006) SPECIAL SALT EFFECT IN MONOMOLECULAR HETEROLYSIS REACTIONS.RUSSIAN JOURNAL OF GENERAL CHEMISTRY. VOL. 76. ISSUE 9. P. 1368-1385 55 93% 3
9 DVORKO, GF , PONOMAREV, NE , PONOMAREVA, EA , (1999) ROLE OF NUCLEOPHILIC SOLVATION IN UNIMOLECULAR HETEROLYSIS.RUSSIAN JOURNAL OF GENERAL CHEMISTRY. VOL. 69. ISSUE 11. P. 1758 -1773 69 91% 4
10 KIM, R , ALI, D , LEE, JP , YANG, K , KOO, IS , (2010) CORRELATION OF THE RATES OF SOLVOLYSIS OF 4-MORPHOLINECARBONYL CHLORIDE USING THE EXTENDED GRUNWALD-WINSTEIN EQUATION.BULLETIN OF THE KOREAN CHEMICAL SOCIETY. VOL. 31. ISSUE 7. P. 1963-1967 44 98% 3

Classes with closest relation at Level 1


Rank Class id link
1 20281 LINEAR FREE ENERGY RELATIONSHIPS//INTRINSIC BARRIERS//ELECTROFUGALITY
2 15243 1 2 ALKYL SHIFTS//6 2 H SHIFTS//ALKYL BRIDGED IONS
3 6692 CROSS INTERACTION CONSTANT//PYRIDINOLYSIS//PHOSPHORYL TRANSFER REACTION
4 18429 9 FLUORENYL CATION//EXCITED STATE CARBON ACIDS//ESTER PHOTOCHEMISTRY
5 22714 BETA ARYL GROUP EFFECT//E2 AND E1CB MECHANISMS//DEHYDROHALOGENATIONS
6 26487 1 ARYL 4 HYDRAZINECARBONYL 2 PYRROLIDINONES//2 2 OXALYLDI 0 SULFOBENZIMIDE//2 BROMOISOBUTYRIC ACID BROBUCOOH
7 33485 N NITROHYDROXYLAMINES//N NITROSOAMIDE//OXIDATIVE NITRATION
8 28827 POLYFLUOROAROMATIC IMIDOYL CHLORIDE DERIVATIVES//1 2 3 4 TETRAHYDROQUINAZOLINE 2 4 DIONES//1 PENTAFLUOROPHENYL 4 6 DIPHENYL 1 3 5 TRIAZINE 2 ONE
9 10471 SN2 REACTION//INVERSION AND RETENTION//MENSHUTKIN REACTION
10 16331 SILYLIUM IONS//CYCLIC VINYLSILANES//SILYLIUM CATIONS

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