Class information for:
Level 1: GAUCHE EFFECT//GATES CRELLIN S CHEM//EXCELLENCE CLUSTER EXC 1003

Basic class information
Class id #P Avg. number of
references		 Database coverage
of references
22083 394 34.1 61%


Bar chart of Publication_year

Last years might be incomplete

Hierarchy of classes
The table includes all classes above and classes immediately below the current class.


Cluster id Level Cluster label #P
5 4 CHEMISTRY, ORGANIC//CHEMISTRY, INORGANIC & NUCLEAR//CHEMISTRY, MULTIDISCIPLINARY 1745167
454 3       JOURNAL OF MOLECULAR STRUCTURE//MICROWAVE SPECTROSCOPY//JOURNAL OF MOLECULAR SPECTROSCOPY 25401
1520 2             MAGNETIC RESONANCE IN CHEMISTRY//SOPPA//ANOMERIC EFFECT 7489
22083 1                   GAUCHE EFFECT//GATES CRELLIN S CHEM//EXCELLENCE CLUSTER EXC 1003 394

Terms with highest relevance score


rank Term termType Chi square Shr. of publ. in
class containing
term		 Class's shr. of
term's tot. occurrences		 #P with
term in
class
1 GAUCHE EFFECT authKW 819926 6% 46% 23
2 GATES CRELLIN S CHEM address 727633 3% 72% 13
3 EXCELLENCE CLUSTER EXC 1003 address 348747 2% 75% 6
4 CLASSICAL EFFECTS authKW 310000 1% 100% 4
5 CRELLIN CHEM address 232494 2% 50% 6
6 WRIGHT RIEMAN CHEM S address 199860 2% 37% 7
7 SOLVATION THEORY authKW 193745 1% 50% 5
8 ORGANOFLUORINE CHEMISTRY authKW 189010 3% 24% 10
9 2 BROMOCYCLOHEXANONE authKW 174374 1% 75% 3
10 FLUOROCYCLOHEXANES authKW 155000 1% 100% 2

Web of Science journal categories


Rank Term Chi square Shr. of publ. in
class containing
term		 Class's shr. of
term's tot. occurrences		 #P with
term in
class
1 Chemistry, Organic 1976 32% 0% 128
2 Chemistry, Physical 1288 39% 0% 153
3 Physics, Atomic, Molecular & Chemical 840 19% 0% 75
4 Chemistry, Multidisciplinary 814 31% 0% 121
5 Spectroscopy 223 7% 0% 28
6 Chemistry, Inorganic & Nuclear 72 6% 0% 23
7 Chemistry, Medicinal 18 3% 0% 11
8 Education, Scientific Disciplines 10 1% 0% 4
9 Crystallography 4 2% 0% 6
10 Mathematics, Interdisciplinary Applications 2 1% 0% 4

Address terms


Rank Term Chi square Shr. of publ. in
class containing
term		 Class's shr. of
term's tot. occurrences		 #P with
term in
class
1 GATES CRELLIN S CHEM 727633 3% 72% 13
2 EXCELLENCE CLUSTER EXC 1003 348747 2% 75% 6
3 CRELLIN CHEM 232494 2% 50% 6
4 WRIGHT RIEMAN CHEM S 199860 2% 37% 7
5 GATES CRELLIN S 155000 1% 100% 2
6 LIQUID CRYSTAL TECH 116247 1% 50% 3
7 LIQUID CRYSTALS RD CHEM 103332 1% 67% 2
8 BUTE BLDG 77500 0% 100% 1
9 DIRETORIA CIENCIAS EXATAS 77500 0% 100% 1
10 DISPLAY RELIABIL CELL TECHNOL 77500 0% 100% 1

Journals


Rank Term Chi square Shr. of publ. in
class containing
term		 Class's shr. of
term's tot. occurrences		 #P with
term in
class
1 BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY 5466 3% 1% 12
2 JOURNAL OF PHYSICAL CHEMISTRY A 3921 10% 0% 39
3 JOURNAL OF FLUORINE CHEMISTRY 3237 4% 0% 17
4 JOURNAL OF PHYSICAL ORGANIC CHEMISTRY 2741 3% 0% 11
5 JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 2407 4% 0% 16
6 MAGNETIC RESONANCE IN CHEMISTRY 1610 3% 0% 11
7 WILEY INTERDISCIPLINARY REVIEWS-COMPUTATIONAL MOLECULAR SCIENCE 1193 1% 1% 2
8 CHEMISTRY-A EUROPEAN JOURNAL 829 4% 0% 16
9 ORGANIC & BIOMOLECULAR CHEMISTRY 787 3% 0% 11
10 SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY 783 3% 0% 13

Author Key Words


Rank Term Chi square Shr. of publ. in
class containing
term		 Class's shr. of
term's tot. occurrences		 #P with
term in
class		 LCSH search Wikipedia search
1 GAUCHE EFFECT 819926 6% 46% 23 Search GAUCHE+EFFECT Search GAUCHE+EFFECT
2 CLASSICAL EFFECTS 310000 1% 100% 4 Search CLASSICAL+EFFECTS Search CLASSICAL+EFFECTS
3 SOLVATION THEORY 193745 1% 50% 5 Search SOLVATION+THEORY Search SOLVATION+THEORY
4 ORGANOFLUORINE CHEMISTRY 189010 3% 24% 10 Search ORGANOFLUORINE+CHEMISTRY Search ORGANOFLUORINE+CHEMISTRY
5 2 BROMOCYCLOHEXANONE 174374 1% 75% 3 Search 2+BROMOCYCLOHEXANONE Search 2+BROMOCYCLOHEXANONE
6 FLUOROCYCLOHEXANES 155000 1% 100% 2 Search FLUOROCYCLOHEXANES Search FLUOROCYCLOHEXANES
7 HALOACETONES 155000 1% 100% 2 Search HALOACETONES Search HALOACETONES
8 SUBSTITUTED ETHANES 155000 1% 100% 2 Search SUBSTITUTED+ETHANES Search SUBSTITUTED+ETHANES
9 HYPERCONJUGATION 106118 4% 8% 17 Search HYPERCONJUGATION Search HYPERCONJUGATION
10 1 3 DISUBSTITUTED CYCLOHEXANES 103332 1% 67% 2 Search 1+3+DISUBSTITUTED+CYCLOHEXANES Search 1+3+DISUBSTITUTED+CYCLOHEXANES

Core articles
The table includes core articles in the class. The following variables is taken into account for the relevance score of an article in a cluster c:
(1) Number of references referring to publications in the class.
(2) Share of total number of active references referring to publications in the class.
(3) Age of the article. New articles get higher score than old articles.
(4) Citation rate, normalized to year.


Rank Reference # ref.
in cl.		 Shr. of ref. in
cl.		 Citations
1 THIEHOFF, C , REY, YP , GILMOUR, R , (2017) THE FLUORINE GAUCHE EFFECT: A BRIEF HISTORY.ISRAEL JOURNAL OF CHEMISTRY. VOL. 57. ISSUE 1-2. P. 92 -100 52 64% 0
2 THIEHOFF, C , SCHIFFERER, L , DANILIUC, CG , SANTSCHI, N , GILMOUR, R , (2016) THE INFLUENCE OF ELECTRONIC PERTURBATIONS ON THE SULFUR-FLUORINE GAUCHE EFFECT.JOURNAL OF FLUORINE CHEMISTRY. VOL. 182. ISSUE . P. 121 -126 22 76% 0
3 O'HAGAN, D , (2012) ORGANOFLUORINE CHEMISTRY: SYNTHESIS AND CONFORMATION OF VICINAL FLUOROMETHYLENE MOTIFS.JOURNAL OF ORGANIC CHEMISTRY. VOL. 77. ISSUE 8. P. 3689-3699 23 62% 32
4 THIEHOFF, C , HOLLAND, MC , DANILIUC, C , HOUK, KN , GILMOUR, R , (2015) CAN ACYCLIC CONFORMATIONAL CONTROL BE ACHIEVED VIA A SULFUR-FLUORINE GAUCHE EFFECT?.CHEMICAL SCIENCE. VOL. 6. ISSUE 6. P. 3565 -3571 27 50% 7
5 ALEKSIC, J , STOJANOVIC, M , BARANAC-STOJANOVIC, M , (2015) ORIGIN OF FLUORINE/SULFUR GAUCHE EFFECT OF BETA-FLUORINATED THIOL, SULFOXIDE, SULFONE, AND THIONIUM ION.JOURNAL OF ORGANIC CHEMISTRY. VOL. 80. ISSUE 20. P. 10197 -10207 26 46% 4
6 BARANAC-STOJANOVIC, M , ALEKSIC, J , STOJANOVIC, M , (2015) ENERGY DECOMPOSITION ANALYSIS OF GAUCHE PREFERENCE IN 2-HALOETHANOL, 2-HALOETHYLAMINE (HALOGEN = F, CL), THEIR PROTONATED FORMS AND ANTI PREFERENCE IN 1-CHLORO-2-FLUOROETHANE.RSC ADVANCES. VOL. 5. ISSUE 29. P. 22980 -22995 28 44% 2
7 SILVA, TFB , ANDRADE, LAF , SILLA, JM , DUARTE, CJ , RITTNER, R , FREITAS, MP , (2014) ENDOCYCLIC OXYGEN IN 3-FLUORODIHYDRO-2H-PYRAN-4(3H)-ONE THAT DOES NOT INDUCE THE GAUCHE EFFECT.JOURNAL OF PHYSICAL CHEMISTRY A. VOL. 118. ISSUE 32. P. 6266 -6271 17 77% 0
8 BUISSONNEAUD, DY , VAN MOURIK, T , O'HAGAN, D , (2010) A DFT STUDY ON THE ORIGIN OF THE FLUORINE GAUCHE EFFECT IN SUBSTITUTED FLUOROETHANES.TETRAHEDRON. VOL. 66. ISSUE 12. P. 2196-2202 23 51% 52
9 BARANAC-STOJANOVIC, M , (2014) GAUCHE PREFERENCE IN 1,2-DIFLUOROETHANE ORIGINATES FROM BOTH ORBITAL AND ELECTROSTATIC STABILIZATION INTERACTIONS.RSC ADVANCES. VOL. 4. ISSUE 83. P. 43834 -43838 19 61% 5
10 HU, XG , THOMAS, DS , GRIFFITH, R , HUNTER, L , (2014) STEREOSELECTIVE FLUORINATION ALTERS THE GEOMETRY OF A CYCLIC PEPTIDE: EXPLORATION OF BACKBONE-FLUORINATED ANALOGUES OF UNGUISIN A.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION. VOL. 53. ISSUE 24. P. 6176 -6179 22 48% 8

Classes with closest relation at Level 1


Rank Class id link
1 11663 ANOMERIC EFFECT//PERLIN EFFECT//SILACYCLOHEXANE
2 26033 CONFORMAT ANAL ELECT INTERACT//STEREOCHEMICAL ISOMERISM//ANAL CONFORMAC ESTUDO INTERACOES ELECT
3 30495 H 1 CHEMICAL SHIFTS//17 KETOSTEROID GLUCURONIDES//1H CHEMICAL SHIFTS
4 20435 F CENTER DOT CENTER DOT CENTER DOT H//POLYFLUORINATED ENAMINOIMINES//AND F CENTER DOT CENTER DOT CENTER DOT F INTERMOLECULAR INTERACTIONS
5 23499 GROUP EQUIVALENTS//SIMULATION OF MASS SPECTRA//BOND EQUIVALENTS
6 2636 FLUORINATION//ELECTROPHILIC FLUORINATION//ANODIC FLUORINATION
7 22597 AMINOACYL INCORPORATION REACTION//BIOMED BIOORGAN CHEM//AMINOACYL INCORPORATION
8 7125 CONFORMATIONAL STABILITY//XENON SOLUTIONS//R0 STRUCTURAL PARAMETERS
9 26674 INFRARED ABSORPTION CROSS SECTIONS//ORBITAL FORCES//GRP CHIM FIS
10 8745 SOPPA//SPIN SPIN COUPLING CONSTANTS//CARBON CARBON SPIN SPIN COUPLING CONSTANTS

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