Class information for:
Level 1: ACYLSILANES//BROOK REARRANGEMENT//ALPHA ACYLOXYSILANE

Basic class information
Class id #P Avg. number of
references		 Database coverage
of references
12565 897 31.6 56%


Bar chart of Publication_year

Last years might be incomplete

Hierarchy of classes
The table includes all classes above and classes immediately below the current class.


Cluster id Level Cluster label #P
5 4 CHEMISTRY, ORGANIC//CHEMISTRY, INORGANIC & NUCLEAR//CHEMISTRY, MULTIDISCIPLINARY 1745167
151 3       CHEMISTRY, INORGANIC & NUCLEAR//PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS//CHEMISTRY, ORGANIC 62986
282 2             POLYSILANE//ORGANOMETALLICS//SILYLENE 18937
12565 1                   ACYLSILANES//BROOK REARRANGEMENT//ALPHA ACYLOXYSILANE 897

Terms with highest relevance score


rank Term termType Chi square Shr. of publ. in
class containing
term		 Class's shr. of
term's tot. occurrences		 #P with
term in
class
1 ACYLSILANES authKW 723185 4% 59% 36
2 BROOK REARRANGEMENT authKW 435692 3% 53% 24
3 ALPHA ACYLOXYSILANE authKW 108927 0% 80% 4
4 ALPHA HYDROXYSILANE authKW 108927 0% 80% 4
5 ANION RELAY CHEMISTRY authKW 106372 1% 63% 5
6 SILYL GLYOXYLATES authKW 102121 0% 100% 3
7 HOMOALLYLIC REARRANGEMENT authKW 76589 0% 75% 3
8 1 4 BROOK REARRANGEMENT authKW 68080 0% 100% 2
9 ALPHA SILYL VINYLSULFIDES authKW 68080 0% 100% 2
10 ALPHA SILYLALDEHYDES authKW 68080 0% 100% 2

Web of Science journal categories


Rank Term Chi square Shr. of publ. in
class containing
term		 Class's shr. of
term's tot. occurrences		 #P with
term in
class
1 Chemistry, Organic 22864 71% 0% 636
2 Chemistry, Multidisciplinary 1365 27% 0% 241
3 Chemistry, Inorganic & Nuclear 310 8% 0% 68
4 Crystallography 1 1% 0% 9
5 Imaging Science & Photographic Technology -0 0% 0% 1
6 Chemistry, Applied -1 1% 0% 5
7 Mathematics, Interdisciplinary Applications -1 0% 0% 2
8 Chemistry, Medicinal -2 0% 0% 4
9 Physics, Atomic, Molecular & Chemical -6 0% 0% 4
10 Biochemical Research Methods -8 0% 0% 1

Address terms


Rank Term Chi square Shr. of publ. in
class containing
term		 Class's shr. of
term's tot. occurrences		 #P with
term in
class
1 ASSOCIE CNRS UMR 6519 68080 0% 100% 2
2 PLANT OURCES CHEM ARID ZONES 49508 0% 36% 4
3 CHIM ORGUMR 34040 0% 100% 1
4 CNRS 7611 34040 0% 100% 1
5 COMPOSTI CARBONIA CONTENENTI ETEROATOMI 34040 0% 100% 1
6 COMPOSTI CARBONIO CONTENENTI ETEROATOMI 34040 0% 100% 1
7 DIPARTIMENTOL CHIM GEN ORGAN PL 34040 0% 100% 1
8 INTERDISCIPLINARY ENGN SCI TECHNOL 34040 0% 100% 1
9 IST CHIM ORGAN VIA G C PONI 9 34040 0% 100% 1
10 IST COMPOSTI CARBONIO ETEROATOMI 34040 0% 100% 1

Journals


Rank Term Chi square Shr. of publ. in
class containing
term		 Class's shr. of
term's tot. occurrences		 #P with
term in
class
1 TETRAHEDRON LETTERS 17588 22% 0% 194
2 JOURNAL OF ORGANIC CHEMISTRY 5814 10% 0% 94
3 ORGANIC LETTERS 5606 7% 0% 65
4 SYNLETT 3624 4% 0% 39
5 SYNTHETIC COMMUNICATIONS 2423 4% 0% 32
6 ORGANIC SYNTHESES 2394 1% 1% 5
7 CHEMISTRY LETTERS 2221 4% 0% 39
8 TETRAHEDRON 2149 5% 0% 49
9 JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 1846 3% 0% 25
10 JOURNAL OF ORGANOMETALLIC CHEMISTRY 1304 4% 0% 33

Author Key Words


Rank Term Chi square Shr. of publ. in
class containing
term		 Class's shr. of
term's tot. occurrences		 #P with
term in
class		 LCSH search Wikipedia search
1 ACYLSILANES 723185 4% 59% 36 Search ACYLSILANES Search ACYLSILANES
2 BROOK REARRANGEMENT 435692 3% 53% 24 Search BROOK+REARRANGEMENT Search BROOK+REARRANGEMENT
3 ALPHA ACYLOXYSILANE 108927 0% 80% 4 Search ALPHA+ACYLOXYSILANE Search ALPHA+ACYLOXYSILANE
4 ALPHA HYDROXYSILANE 108927 0% 80% 4 Search ALPHA+HYDROXYSILANE Search ALPHA+HYDROXYSILANE
5 ANION RELAY CHEMISTRY 106372 1% 63% 5 Search ANION+RELAY+CHEMISTRY Search ANION+RELAY+CHEMISTRY
6 SILYL GLYOXYLATES 102121 0% 100% 3 Search SILYL+GLYOXYLATES Search SILYL+GLYOXYLATES
7 HOMOALLYLIC REARRANGEMENT 76589 0% 75% 3 Search HOMOALLYLIC+REARRANGEMENT Search HOMOALLYLIC+REARRANGEMENT
8 1 4 BROOK REARRANGEMENT 68080 0% 100% 2 Search 1+4+BROOK+REARRANGEMENT Search 1+4+BROOK+REARRANGEMENT
9 ALPHA SILYL VINYLSULFIDES 68080 0% 100% 2 Search ALPHA+SILYL+VINYLSULFIDES Search ALPHA+SILYL+VINYLSULFIDES
10 ALPHA SILYLALDEHYDES 68080 0% 100% 2 Search ALPHA+SILYLALDEHYDES Search ALPHA+SILYLALDEHYDES

Core articles
The table includes core articles in the class. The following variables is taken into account for the relevance score of an article in a cluster c:
(1) Number of references referring to publications in the class.
(2) Share of total number of active references referring to publications in the class.
(3) Age of the article. New articles get higher score than old articles.
(4) Citation rate, normalized to year.


Rank Reference # ref. in
cl.		 Shr. of ref. in
cl.		 Citations
1 ZHANG, HJ , PRIEBBENOW, DL , BOLM, C , (2013) ACYLSILANES: VALUABLE ORGANOSILICON REAGENTS IN ORGANIC SYNTHESIS.CHEMICAL SOCIETY REVIEWS. VOL. 42. ISSUE 21. P. 8540 -8571 159 48% 32
2 PATROCINIO, AF , MORAN, PJS , (2001) ACYLSILANES AND THEIR APPLICATIONS IN ORGANIC CHEMISTRY.JOURNAL OF THE BRAZILIAN CHEMICAL SOCIETY. VOL. 12. ISSUE 1. P. 7 -31 70 67% 53
3 SASAKI, M , IKEMOTO, H , TAKEDA, K , (2009) DEVELOPMENT OF EPOXYSILANE REARRANGEMENT AND ITS APPLICATION TO CHIRALITY TRANSFER.HETEROCYCLES. VOL. 78. ISSUE 12. P. 2919 -2941 31 78% 5
4 NAKAI, Y , KAWAHATA, M , YAMAGUCHI, K , TAKEDA, K , (2007) STEREOCONTROLLED CONSTRUCTION OF SEVEN-MEMBERED CARBOCYCLES USING A COMBINATION OF BROOK REARRANGEMENT-MEDIATED [3+4] ANNULATION AND EPOXYSILANE REARRANGEMENT.JOURNAL OF ORGANIC CHEMISTRY. VOL. 72. ISSUE 4. P. 1379 -1387 31 78% 5
5 MOSER, WH , (2001) THE BROOK REARRANGEMENT IN TANDEM BOND FORMATION STRATEGIES.TETRAHEDRON. VOL. 57. ISSUE 11. P. 2065-2084 38 57% 198
6 RICCI, A , DEGL'INNOCENTI, A , (1989) SYNTHESIS AND SYNTHETIC POTENTIAL OF ACYLSILANES.SYNTHESIS-STUTTGART. VOL. . ISSUE 9. P. 647 -660 40 75% 193
7 YAN, LJ , SUN, XW , LI, HZ , SONG, ZL , LIU, ZJ , (2013) GEMINAL BIS(SILYL) ENAL: A VERSATILE SCAFFOLD FOR STEREOSELECTIVE SYNTHESIZING C-3,O-1-DISILYLATED ALLYLIC ALCOHOLS BASED UPON ANION RELAY CHEMISTRY.ORGANIC LETTERS. VOL. 15. ISSUE 5. P. 1104 -1107 29 57% 5
8 PAGE, PCB , KLAIR, SS , ROSENTHAL, S , (1990) SYNTHESIS AND CHEMISTRY OF ACYL SILANES.CHEMICAL SOCIETY REVIEWS. VOL. 19. ISSUE 2. P. 147-195 45 62% 193
9 CLAYDEN, J , WATSON, DW , CHAMBERS, M , (2005) CAN RELIEF OF RING-STRAIN IN A CYCLOPROPYLMETHYLLITHIUM DIVE THE BROOK REARRANGEMENT?.TETRAHEDRON. VOL. 61. ISSUE 13. P. 3195-3203 26 70% 21
10 TAKEDA, K , (2007) DEVELOPMENT OF NEW SYNTHETIC REACTIONS FEATURING TANDEM CARBON-CARBON BOND FORMATION.YAKUGAKU ZASSHI-JOURNAL OF THE PHARMACEUTICAL SOCIETY OF JAPAN. VOL. 127. ISSUE 9. P. 1399 -1418 24 73% 2

Classes with closest relation at Level 1


Rank Class id link
1 8593 ALLYLSILANES//SILYLCUPRATION//PROPARGYLSILANES
2 23732 CHIRAL SILANOL//1 TRIMETHYLSILYL ETHANOL//POLYMERS ENGN NANOMAT
3 23761 1 1 3 3 5 5 HEXAMETHYL 1 3 5 TRISILACYCLOHEXANE//1 3 5 8 10 13 HEXASILABICYCLO722TRIDEC 6 YNE//2 2 9 TRIBROMO 1 3 3 5 5 8 8 10 10 13 13 UNDECAMETHYL
4 7914 SPARTEINE//CARBOLITHIATION//HOMOALDOL REACTION
5 21851 TRISYL//TRISTRIMETHYLSILYLMETHYLLITHIUM//ORGANOSILICON
6 21175 CINMPIS//DIPARTIMENTO FARMACOCHIM//OXIRANYLLITHIUMS
7 30849 PROPARGYLIC DITHIOACETALS//ZWITTERION SYNTHON//OLIGOARYLS
8 23593 SILA DRUGS//FRAGRANCE//SILA SUBSTITUTION
9 11282 HYDROSTANNATION//HYDROSTANNYLATION//VINYLSTANNANES
10 18699 STEVENS REARRANGEMENT//AMMONIUM YLIDE//SOMMELET HAUSER REARRANGEMENT

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